Inorganic Syntheses, Volume 35

Inorganic Syntheses, Volume 35

Rauchfuss, Thomas

John Wiley & Sons Inc

10/2010

224

Dura

Inglês

9780471682554

15 a 20 dias

432

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Preface. Contributors.

Dedication.

Notice to Contributors and Checkers.

Toxic Substances and Laboratory Hazards.

Chapter One COMPLEXES OF BULKY ss-DIKETIMINATE LIGANDS.

1. Introduction.

2. ss-Diketiminate Precursors HLMe,Me3 and TlLMe,Me3 (LMe,Me3 = 2,4-Bis-(Mesitylimido)Pentyl).

3. ss-Diketiminate Precursors LMe,iPr2H, [LMe,iPr2Li]x, and [LtBu,iPr2K]x (LMe,iPr2 = 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl; LtBu,iPr2 = 2,2,6,6-

Tetramethyl-3,5-Bis-(2,6-Diisopropylphenylimido)Heptyl).

4. ss-Diketiminate Precursors LtBu,iPr2H and LtBu,iPr2Li(THF) (LtBu,iPr2=2,2,6,6-Tetramethyl-3,5- Bis-(2,6-Diisopropylphenylimido)Heptyl).

5. Scandium Trichloride Tris(Tetrahydrofuran) and ss-Diketiminate-Supported Scandium Chloride Complexes.

6. ss-Diketiminate-Supported Titanium and Vanadium Dichloride Complexes.

7. ss-Diketiminate-Supported Vanadium and Chromium Chloride Complexes.

8. ss-Diketiminate-Supported Manganese and Zinc Complexes.

9. Iron 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl Chloride (LMe,iPr2FeCl).

10. Iron 2,2,6,6-Tetramethyl-3,5-Bis-(2,6-Diisopropylphenylimido)Heptyl Chloride (LtBu,iPr2FeCl).

11. Cobalt 2,2,6,6-Tetramethyl-3,5-Bis-(2,6-Diisopropylphenylimido) Heptyl Chloride (LtBu,iPr2CoCl).

12. ss-Diketiminate-Supported Nickel(II) and Nickel(I) Complexes of LMe,Me3 (LMe,Me3 = 2,4-Bis-(Mesitylimido)Pentyl).

13. Nickel 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl Chloride Dimer, [LMe,iPr2Ni(?-Cl)]2.

14. Bis[Copper 2,4-Bis-(2,4,6-Trimethylphenylimido)Pentyl] Toluene, (LMe,Me3Cu)2(?-n2:n2-C7H8).

15. Copper 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl Chloride (LMe,iPr2CuCl).

Chapter Two BORON CLUSTER COMPOUNDS.

16. Salts of Dodecamethylcarba-closo-Dodecaborate(-) Anion, CB11Me12, and the Radical Dodecamethylcarba-closo-Dodecaboranyl, CB11Me12.

17. Cesium Dodecahydroxy-closo-Dodecaborate, Cs2[B12(OH)12].

Chapter Three COORDINATION COMPOUNDS.

18. Pentaaquanitrosylchromium Sulfate.

19. The Tetradentate Bispidine Ligand Dimethyl-(3,7-Dimethyl-9-oxo-2,4-bis(2-pyridyl)-3,7-Diazabicyclo[3.3.1]nonane)-1, 5-dicarboxylate and Its Copper(ll) Complex.

20. Tris(2-Picolinyl)Methane and Its Copper(I) Complex.

Chapter Four CARBENE LIGANDS AND COMPLEXES.

21. 1,3-Dialkyl-Imidazole-2-Ylidenes.

22. A Chelating Rhodium N-Heterocyclic Carbene Complex by Transmetallation from a Silver-NHC Intermediate.

23. Rhodium and Iridium N-Heterocyclic Carbene Complexes from Imidazolium Carboxylates.

Chapter Five FUNCTIONAL LIGANDS AND COMPLEXES.

24. N-tert-Butyl ortho-Aminophenol, ortho-Iminoquinone, and a Zirconium(IV) bis(Aminophenolate) Complex.

25. Synthesis of the Water-Soluble Bidentate (P, N) Ligand PTN(Me) (PTN(Me) = 7-Phospha-3-methyl-1,3,5-triazabicyclo[3.3.1]nonane).

26. Synthesis of Metal-Organic Frameworks: MOF-5 and MOF-177.

Chapter Six ORGANOMETALLIC REAGENTS.

27. Tricarbonyl 1,3,5-Trimethyl-1,3,5-Triazacyclohexane Complexes of Chromium(0), Molybdenum(0), and Tungsten(0) [M(CO)3(Me3TACH) (M = Cr, Mo, W)].

28. Manganese Tricarbonyl Transfer (MTT) Agents.

29. Bis(1,5-Cyclooctadiene)Nickel(0).

30. Sodium (n5-Cyclopentadienyl)Tris(Dimethylphosphito-P) Cobaltate(III), Na[(C5H5)Co{P(O)(OMe)2}3].

Chapter Seven BIO-INSPIRED IRON AND NICKEL COMPLEXES.

31. Iron-Cyanocarbonyl Complexes [PPN][Fe(CO)4(CN)] and [PPN][FeBr(CO)3(CN)2].

32. Nickel Complexes of Bis(Diethylphosphinomethyl) Methylamine.

33. Monomeric Iron(II) Complexes Having Two Sterically Hindered Arylthiolates.

34 (1,3-Propanedithiolato)-Hexacarbonyldiiron and Cyanide Derivatives.

Chapter Eight RUTHENIUM COMPLEXES.

35. Ruthenium(II)-Chlorido Complexes of Dimethylsulfoxide.

36. Synthesis of Chloride-Free Ruthenium(II) Hexaaqua Tosylate, [Ru(H2O)6]tos2.

37. Basic Ruthenium Acetate and Mixed Valence Derivatives.

38. Di-?-Chloro(Ethylbenzoate)Diruthenium(II), [(n6-etb)RuCl2]2.

Chapter Nine IRIDIUM COMPLEXES.

39. The Diphosphine tfepma and its Diiridium Complex Ir20,II(tfepma)3Cl2.

40. Heteroleptic Cyclometalated Iridium(III) Complexes.

41. Oxygen and Carbon Bound Acetylacetonato Iridium(III) Complexes.

Contributor Index.

Subject Index.

Formula Index.
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notice; bulky; ligands; complexes; precursors; trichloride; chloride; scandium; dichloride complexes; lme; boron; two; dodecamethylcarbaclosododecaborate anion; compounds; coordination; three