Organic Syntheses V82

Organic Syntheses V82

John Wiley & Sons Inc

12/2005

272

Dura

Inglês

9780471682561

15 a 20 dias

480

Descrição não disponível.
Preparation of 1,4:5,8-Dimethano-1,2,3,4,5,6,7,8-Octahydro-9,10-Dimethaoxyanthracenium Hexachiloroantimonate(4+Sbcl6-): A Highly Robust Radical-Cation Salt. Preparation of Optically Active (R,R)-Hydrobenzoin From Benxoin or Benzil. 2,2-Diethoxy-1-Isoxyanoethane. Preparation of (S,S) -1,2--BIS(tert-Butylmethylphosphino)-Ethane ((S,S)-t-Bu-BISP) As a Rhodium Complex. Preparation of Hexakis(4-Bromophenyl)Benzene (HBB). An Efficient, Highly Diastereo- And Enantioselective Hetero-Diels-Alder Catalyst. Preparation of (2S, 6R)-6-(tert-Butyldimethylsilyloxymethyl)-2-Methoxy-2,5-Diyhdropyran. Lipase-Catalyzed Resolution of 4-Trimethylsilyl-3-Butyn-2-OL and Conversion of the (R)-Enantiomer To (R)-3-Butyn-2-Yl Mesylate and ({)-1-tributylstannyl-1,2-Butadiene. Iridium-Catalyzed Synthesis of Vinyl Ethers from Alcohols and Vinyl Acetate. 1-(tert-Butyliminomethyl)-1,3-Dimethylurea Hydrochloride. Ortho-Formylation of Phenols: Preparation of 3-Bromosalicylaldehyde. Preparation of 1-Methoxy-2-(4-Methoxyphenoxy)Benzene. D-Ribonolactone and 2,3-Isopropylidene-(D-Ribonolactone) Preparation of 4-Acetylamino-2,2,6,6-Tetramethyl-Piperidine-1-Oxoammonium Tetrafluoroborate, and the Oxidation of Geraniol to Geranial. (2S)-(-)-3exo-(Morpholino)Isoborneol [(-)-MIB]. Conversion of Arylalkylketones Into Dichloroalkenes: 1-Chloro-4-(2,2-Dichloro-1-Methylvinyl)Benzene. 1,4,-Dioxene. (R)-(+)-3,4-Dimethylcyclohex-2-EN-1-One. A Practical and Safe Preparation of 3,5-BIS-(Trifluoromethyl)Acetophenone. Asymmetric Alcoholysis of Meso-Anhydrides Mediated By Alkaloids. Iridium-Catalyzed C-HBorylation of Arenes and Heteroarenes: 1-Chloro-3-Iodo-5-(4,4,5,5-Tetramethyl-1,3,2,-Dioxaborolan-2-YL)Benzene and 2-(4,4,5,5-Tetramethyl-1,3,2-Dioxaborolan-2-YL)Indole. Asymmetric Rearrangement of Allylic Trichloroacetimidates: Preparation of (s)-2,2,2-Trichloro-N-(1-Propylallyl)Acetamide. Preparation of (Triphenylphosphoranylidene)-Ketene From (Methoxycarbonylmethylene)-Triphenylphosphorane. Preparation of [1-(Methoxymethylcarbamoyl)-Aethyl]Phosphonic Acid BIS(2,2,2-Trifluoroethyl)Ester: A Useful Intermediate in the Synthesis of Z-Unsaturated N-Methoxy-N-Methylamides. (Rs)-(+)-2-Methyl-2-Propanesulfinamide. Preparation of 1-Butyl-3-Methylimidazolium Tetrafluoroborate. Catalytic Asymmetric Acyl Halide-Aldehyde Cyclocondensation reaction. Alkyne via Solid-Liquid Phase-Transfer Catalyzed Dehydrohalogenation: Acetylene Dicarboxaldehyde Tetramethyl Acetal and Acetylene Dicarboxaldeyde Dimethyl Acetal. Catalytic reduction of Amides to Amines with Hydrosilanes Using a Tributhenium Carbonyl Cluster as the Catalyst.
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dimethaoxyanthracenium; radicalcation; robust; hexachiloroantimonate; optically; preparation; complex; rhodium; hbb; hexakis; heterodielsalder; trimethylsilyl butyn; resolution; lipasecatalyzed; yl; synthesis; ethers